Conformational flexibility of palladium BINAP complexes explored by X-ray analyses and DFT studies
نویسندگان
چکیده
منابع مشابه
Structure, bonding, and reactivity of Ti and Zr amidate complexes: DFT and X-ray crystallographic studies.
Easily prepared and highly modular organic amide proligands have been used to synthesize a series of new bis(amidate)-bis(amido) Ti and Zr complexes via protonolysis. These complexes have been structurally characterized by NMR spectroscopy and X-ray crystallography. The solid-state molecular structures of these complexes indicate that the amidate ligands bind to the metal centers in an exclusiv...
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OBJECTIVE The purpose of this study was to use x-ray diffraction (XRD) to obtain new information about the oxide layers on four representative oxidized high-palladium alloys. METHODS Cast specimens of two Pd-Cu-Ga alloys and two Pd-Ga alloys, with both polished and etched surfaces and air-abraded surfaces, were subjected to oxidation procedures recommended by the manufacturers. The specimens ...
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ژورنال
عنوان ژورنال: Polyhedron
سال: 2013
ISSN: 0277-5387
DOI: 10.1016/j.poly.2012.11.016